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two or three ounces thrice every day, which are gradually augmented, until a pint is at length consumed daily. When there is a degree of torpor in the superficial vessels, the same decoction, made with a larger proportion of the shrub, is advantageously employed as a lotion; but if there is much inflammatory disposition, this and every other external stimulus must be prohibited.

"Where this irritable state of the disease exists, indeed, (and it is the most frequent,) nothing more stimulating than tepid water, or thin gruel, can be used for the purposes of ablution; and the arseniates, pitch, &c. above mentioned, must be excluded. The disease, under this condition, will be certainly aggravated by sea-bathing, by the external use of the strong sulphureous waters, or of any irritant, as I have frequently observed; but it will be alleviated by the internal employment of sulphur, with soda or nitre, or the hydrarg. sulphuratus niger with an antimonial, especially when conjoined with the decoction of dulcamara. The caustic potass, or liquor potasse of the L. Pharmacopoeia, in the dose of twenty or thirty drops, alone, or in combination with the precipitated sulphur, is likewise beneficial; and the tinctura veratri, given in such doses as not to disorder the bowels, has occasionally removed this state of the disease.

"When the skin is highly inflamed, thickened, and stiff, of a vivid red color, intermixed with a yellowish hue, (where the cuticle is separating in large flakes,) the heat, pain, and itching are often extremely troublesome, and the motion of the limbs is almost impracticable. The most effectual relief is obtained, in these cases, by gently besmearing the parts with cream, or a little fresh and well washed lard, or butter.

"3. Lepra nigricans is a more rare variety of the disease, differing externally from the L. vulgaris chiefly in the dark and livid hue of its patches, which is most obvious in the margin, but even appears through the thin scales in the area of each patch.* The scales are more easily detached in this form of lepra, and the surface remains longer tender, and is often excoriated, discharging bloody serum, till a new incrustation is formed.

"This variety of lepra occurs in persons whose occupations expose them to the vicissitudes of the weather, and to a precarious diet, with fatigue, and watching. It is cured by nutritive food, with moderate exercise, followed by the use of the bark, mineral acids, and seabathing."

*The Melas of the ancients was deemed a superficial affection, resembling the Alphos, except in its color. Maç colore ab hoe differt, quia niger est, et umbræ similis: cætera eadem sunt.' (Celsus, loc. cit.) Possibly it included the Pityriasis versicolor."

MEDICAL

MEDICAL AND PHILOSOPHICAL INTELLIGENCE.

ROYAL SOCIETY-On Thursday the 1st of July, a paper by Sir Humphry Davy was read, containing farther observations on the new detonating compound of chlorine and azote. After recovering from the accident which happened to him during his original experiments on this substance, Sir Humphry made a variety of expetiments to determine its properties and composition. Its specific gravity is 1.623. When in contact with water, it congeals at about 40°; but this does not happen when it is kept separate from water. It detonates in nitric acid, and in ammonia; gives out azote in muriatic acid; and is likewise decomposed in sulphuric acid. Attempts were made to decompose it in exhausted glass vessels in the state of vapor; but they were unsuccessful. In general, the glass was broken by an explosion; and when that did not happen, the proportion of chlorine and azote evolved could not be determined, on account of the unknown proportion of atmospheric air that remained in the vessel. When the detonating compound is brought in contact with mercury, a white powder is formed, and azotic gas disengaged. In one experiment a detonation took place, which obliged him to work upon smaller quantities. The white powder was found to be a mixture of calomel and corrosive sublimate; and it sublimed entirely without the disengagement of any gas, indicating the absence both of hydrogen and oxygen. Muriatic acid does not destroy the color of solution of indigo in sulphuric acid; but if it be impregnated with chlorine, it destroys a determinate quantity of the blue color, according to the proportion of chlorine present. The same thing happens when the detonating compound is dissolved in muriatic acid. This furnished a method for determining the proportion of chlorine contained in the detonating compound. The result of all these methods of analysis is, that the detonating compound is composed of

Chlorine
Azote

91

9

100

reckoning by weight, or if we reckon by bulks of

Chlorine
Azotic gas

400

100

500

Sir H. Davy proposes to call this detonating compound azotane. At the same meeting were read some observations on a new comet, observed by Captain Hill, in the Hon. East India Company's

service.

On Thursday, the 8th of July, the following papers were read: 1. A catalogue of the positions of a number of circumpolar stars by the Astronomer Royal, Mr. Pond.

2. An analysis of a substance thrown out of Mount Vesuvius, by

3

James

James Smithson, Esq, This substance had been sent to Mr. Smithson when in Italy in 1794, in order to determine its nature; and he ascertained, by a number of trials, that it consisted chiefly of sulphate of potash. This result was published soon after in an Italian Journal, but no subsequent notice was taken of it by mineralogists. Mr. Smithson was induced to examine it with more accuracy lately, and the result of his experiments is, that it consists of sulphate of potash, sulphate of soda, sulphate of ammonia, muriate of ammonia, muriate of copper, and muriate of iron, with some earthy matter. Mr. Smithson, by way of introduction to his paper, gives a view of his opinions about the origin of the earth. In his opinion, it was originally a sun, or a comet, and was brought to the state in which it is at present by undergoing combustion at the surface. The volcanoes are the relics of this original combustion, and the materials were the metallic bases of the earthy substances of which the primitive strata are composed. As a proof that these primitive strata have been formed by combustion, he mentions that garnets, hornblende, and other crystals found in them, contain no water, and that little or no water is to be found in the primitive strata themselves.

3. Observations, by Dr. Marcet, on the cold produced by the evaporation of sulphuret of carbon. This liquid evaporates more rapidly than any other, and produces in consequence a greater degree of cold. A spirit of wine thermometer, having its bulb surrounded with cotton cloth or lint, if dipped into sulphuret of carbon, and suspended in the air, sinks from 600 to 0. If it be put into the receiver of an air-pump, and a moderate exhaustion be made, it sinks from 60° to 81° (I have seen it myself in these circumstances sink from 74° to - 72°). If a tube containing mercury be treated in the same way, the mercury may be readily frozen, even in summer. The drier the air in the receiver is, the more easily is the cold produced. Hence the presence of sulphuric acid may be of some little service in removing the vapor from the air in the receiver previous to exhaustion; otherwise it occasions no increase of the cold.

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4. Observations on the composition of fluor spar, and on its acid basis, by Sir Humphry Davy. The author begins his paper with an historical detail of the attempts made by himself, and Gay-Lussac and Thenard, to decompose fluoric acid, and the ill success of these attempts. It appears from the compounds into which fluoric acid enters, that the weight of an integrant particle of it does not exceed 1.05, supposing an atom of oxygen to weigh 1. Hence it follows that if it is a compound of oxygen and an inflammable base, the base can only have the 20th part of the weight of the oxygen. This supposition he considers as unlikely to be correct. He therefore supposes that fluoric acid, like muriatic acid, is a compound of hydrogen and an unknown supporter of combustion, to which he gives the name of fluorine. He relates many experiments made in order to obtain fluorine in a separate state, but none of them were attended with success. chlorine has the property of decomposing several oxides, and driving off their oxygen, it occurred to him as likely that it might in certain

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cases

cases drive off fluorine. Fluate of silver and fluate of mercury, with this view, were acted upon by chlorine. The fluoric acid (or fluorine) was disengaged, and horn silver and corrosive sublimate formed; but no fluorine was set free. When the experiments were made in glass retorts, the glass was corroded, and silicated fluoric acid gas obtained. When they were made in platinum vessels, the metal was corroded, and a red or brown powder formed. It would seem from the trials made that fluorine has so violent an action on all other bodies that it is very difficult, if not impossible, to obtain it in a separate state. The author promises to continue this subject in a subsequent paper.

5. A paper, by Mr. Alman, on the method of treeing equations from surds, though the roots be pretty high in their dimensions. From the nature of this paper it could not be read at full length, so that it is not possible to give any idea of the method employed by the author; but he referred to a method previously given in the Irish Transactions by Mr. Money, which he considers as general, and which, probably, constitutes the foundation of his own.

The Society adjourned till the 4th of November next.

Galvanic Buttery-On Saturday, the 2d of July, J. G. Children, esq. put in action the greatest galvanic battery that has ever been constructed. It consisted of 20 pair of copper and zinc plates, each plate 6 feet in length, 2 feet 8 inches in breadth. Each pair was fixed together at the top by pieces of lead cut into ribbons. A separate wooden cell was constructed for each pair. The plates were suspended from a wooden beam fixed at the ceiling, and were so hung by means of counterpoises that they could be easily raised or let down into the cells. The cells were filled with water, containing a mixture of sulphuric and nitric acids. At first the acids amounted to 1-60th of the water; but more was gradually added till it amounted to the 30th. Leaden pipes were attached to the two extremities of the battery, and conveyed the electricity out of doors to an adjoining shade, where the experiments were made. The power of this battery was very great; though I am not certain whether it increased in proportion to the size of the plates. It ignited about 6 feet in length of thick platinum wire. The heat produced was very intense. It melted platinum with great facility. Iridium was likewise melted into a globule, and proved to be a brittle metal. The ore of iridium and osmium was likewise melted, but not so completely. Charcoal was kept in a white heat in chlorine gas, and in phosgene gas; but no change took place in either of these gases. Neither tungsten nor uranium underwent any change. A very singular fact was pointed out by the sagacity of Dr. Wollaston, and succeeded upon trial. greater length of thick platinum wire was ignited than of platinum wire of a much smaller size. This Dr. Wollaston had previously ascertained in his own minute galvanic batteries, consisting of a single pair of small plates.

A

Volatility of Cerium.-The volatility of this metal, which had been previously inferred from the experiments of Vauquelin, was fully confirmed in Mr. Children's laboratory at Tonbridge. A quan

tity of oxalate of cerium had been prepared in order to obtain from it the oxide of the metal. This oxalate was exposed in a charcoal crucible within a tobacco-pipe mouth to the strongest heat that could be raised in a forge. In this heat the cerium was volatilized so completely that not the least trace of it remained.

Action of the Agate on Light.-D. Brewster has now established, by numerous experiments, that the nebulous light of the agate has the same relation to the bright image as the extraordinarily refracted image has to the ordinarily refracted image of all doubly refracting crystals. There is still, however, no appearance of the nebulous light being produced by a higher refractive power than the bright image. All the phenomena of polarization are produced when the plate of agate is less than the oth of an inch; and the nebulous light, when in its evanescent state, can be revived by depolarization with mica, in every respect like one of the images formed by double refraction. The colored appearances in the agate, to which mineralogists have given the name of iridescence, furnish a series of the most singular results, arising, apparently, from the mechanical structure of different lamine, and seem to open up a new field in physical optics. He is at present examining various specimens, in order to give a greater degree of generality to the results previous to laying them before the public.

An Account of the Explosion of Inflammable Air which lately occurred in the Collingwood Main Colliery.

On Saturday the 17th of July, at two o'clock, p. m. in the Collingwood Main Colliery, situated upon the river Tyne, near North Shields, a very considerable quantity of inflammable air, or carbureted hydrogen gas, came into contact with the pitmen's candles, which caused a most tremendous explosion, by which eight persons were killed upon the spot, and two severely wounded and scorched. The following particulars of this melancholy disaster were communicated verbatim at the above-mentioned colliery, a few days after the accident, to the writer of this, by Henry Hall, who fortunately escaped, though in the midst of imminent danger.

At the time when the explosion took place, the above-named Henry Hall, and five other pitmen, were proceeding with burthens of timber through the old workings or excavations (the proper road being obstructed by a creep,*) in the full confidence of safety, having been assured by Mr. Hope, the under viewer, that there was no fear of the "mine firing.' In an instant this young man, Henry Hall, and the five pitmen who were with him, were by the explosion thrown upon their faces; and the shock was so great as to deprive him of sensation, as well as volition, till the after-blast, or after-damp, as it

ور

*In working the coal, the pitmen leave pillars, in the form of parallelograms, for the support of the roof. If these pillars are narrow, and the floor of the mine soft or tender, they are apt to sink into the floor, and cause such an approximation as to prevent ventilation, &c. This is technically called a creep.

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